In this study, porous starch (PS) from cassava starch (CS) and faba bean
starch (FS) was prepared using ultrasound (US) as pretreatment prior to
enzymatic treatment followed by alcohol alkaline treatment (GCWS) to improve
properties of modified starch. The effect of these methods on morphological,
ratio of 1047/1022 spectra by FTIR, thermal properties, particle size
distribution, solubility and adsorption capacity were studied and compared.
The result showed that the surface of PS presented rough surface with small
pores on the surface of both starch granules. US-PS and US-PS-GCWS modified
samples showed more porous structure on the surface especially observed on
CS. The modified PS samples displayed altered significant reduced in
relative crystallinity (44.23% - 20.56% reduction) while maintaining their
chemical structure as confirmed by FTIR analysis. Compared with unmodified
PS, cold water solubility increased by 72.05% and 58.79% for US-PSC-GCWS and
US-PSF-GCWS respectively. The water adsorption capacity also increased by
30.56% and 27.66% for US-PS-GCWS on both starches compared to PS alone. All
modified PS samples scored higher encapsulation efficiency compared to PS
with triple modification achieved highest efficiency and thermal stability
for both modified starches. The findings demonstrated that triple
modification (US-PS-GCWS) effectively improved the structural integrity,
adsorption capacity and encapsulation efficiency of starch, highlighting its
potential as a sustainable carrier for thermally sensitive bioactive
compounds in functional food application.